Effect of thermal activation on the tribological behaviors of muscovite particles as lubricant additives in lithium grease

Abstract

Purpose The tribological properties of muscovite and its thermal-treated products as lubricant additives in lithium grease were investigated. The effect of thermal temperature on the crystal structure and tribological properties of muscovite was studied. This study aims to explore the tribological mechanism of muscovite and optimize a proper thermal activation temperature, thus further improving the tribological properties. Design/methodology/approach The crystal structure of muscovite samples was characterized by SEM, TG-DSC, XRD and FTIR. The tribological properties of grease samples were investigated using a four-ball tribotester and the worn surface was analyzed by SEM and EDS. Findings The excellent tribological properties of muscovite can be ascribed to the layer structure and lubricant film formed on the worn surface. Thermal temperature at 500-600°C increases the surface activity and oxygen releasing capability, and thus favors the formation of lubricant film and accordingly further improves the tribological properties. However, the layer structure is destroyed and hard phases such as alumina and amorphous appear after thermal temperature activated beyond 1000°C, as it results in the aggravation of friction and wear. Originality/value To the authors’ knowledge, it is the first to study the effect of thermal temperature on the crystal structure and tribological properties of muscovite. The tribological mechanism of muscovite particle and its thermal-treated products was disclosed.