Melamine-urea-formaldehyde resins with low formaldehyde emission and resistance to boiling water

Abstract

Purpose The purpose of the study was to prepare melamine-urea-formaldehyde (MUF) resin that would be resistant to boiling water and high temperature and exhibit low formaldehyde emission. Design/methodology/approach The authors prepared MUF resin with different F/(M + U) and changed the amount of melamine added, through the analysis of MUF resin properties to get the best reaction parameters, and used different amino acid cure systems including NH4Cl cured the resin. Findings Resin’s heat resistance and water resistance are mainly determined by the amount of melamine added, and formaldehyde emission of the plywood can be changed by adjusting F/(M + U). The peak temperature of the curing agent-cured resin increases as compared with the self-curing resin. Stronger the acidity of curing agent, faster the viscosity increased in probation period and lower the bonding strength and heat resistance of the resin. Research limitations/implications Melamine improves the heat resistance and water resistance of the resin. When the amount of melamine is more than a certain value, water resistance of the resin decreased. Practical implications MUF resin that is resistant to boiling water and exhibits low formaldehyde emission can be used in high temperature, high humidity and strict formaldehyde emission environment and can also be combined with other materials. Social implications It was helpful to reduce the effect of formaldehyde emission on people’s health and environmental pollution and is also beneficial for the expansion of the application range of aldehyde resin. Originality/value The originality is twofold: the influence of the acid strength of curing agent on the bonding strength of the resin adhesive and the method for preparing high performance MUF resin by following the traditional process.