Comparative study on cross-linked fluorocarbon acrylate latex

Author:

Zhao Wanting,Chen Lijun

Abstract

Purpose Self-crosslinked long fluorocarbon acrylate polymer latex has good hydrophobic and oleophobicity, weather resistance, aging resistance, stability and other excellent properties, which make the polymer be widely used in coatings, dyes, adhesives and other products. The purpose of this study is to prepare self-crosslinked long fluorocarbon acrylate polymer latex via semi-continuous seeded emulsion technology and carry out comparative study on two different cross-linked monomers. Design/methodology/approach Methyl methacrylate (MMA) and butyl acrylate (BA) were used as the main monomers, dodecafluoroheptyl methacrylate (DFMA) as the fluoromonomer, hydroxypropyl methacrylate (HPMA) and N-methylol acrylamide (NMA) as cross-linked monomers, and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether (ANPEO10) and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether ammonium sulfate (DNS-86) as compound emulsifiers via the semicontinuous-seeded emulsion polymerization. Findings The properties of the polymer emulsions, which are prepared with two different cross-linked monomers, are compared and discussed, and it is concluded that HPMA is more suitable for the preparation of self-crosslinked polymer emulsions. The formula of the polymer latex is ANPEO10: DNS-86 = 1:1, and the mass ratio of the monomers used in the polymer is MMA: BA: DFMA: HPMA = 14.40:14.40:0.60:0.60. Practical implications Self-crosslinked long fluorocarbon acrylate polymer latex can be used in many fields such as coatings, dyes, adhesives and other products. Originality/value The self-crosslinked long fluorocarbon acrylate polymer latex is prepared by mixing the nonionic emulsifier ANPEO10 and the anionic emulsifier DNS-86 when potassium persulfate is used as the thermal decomposition initiator and the semicontinuous-seeded emulsion technology is adopted and the comparative study on two different cross-linked monomer is carried out, which is not reported in the open literatures.

Publisher

Emerald

Subject

Materials Chemistry,Surfaces, Coatings and Films

Reference20 articles.

1. Properties and characterization of acrylic latex prepared with novel emulsifiers;Polymers from Renewable Resources,2018

2. Preparation of self-crosslinked acrylate latex with high elasticity and its rheological properties;Journal of Central South University of Technology,2008

3. Preparation and characterization of green acrylic latex modified with fluorinated and cross-linked monomers;Journal of Polymer Materials,2017

4. Study of self-crosslinking acrylate latex containing fluorine;Journal of Applied Polymer Science,2003

5. Synthesis and application of self-crosslinked acrylate modified soap-free emulsion;Dyeing and Finishing Technology,2014

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