Enhancing mortar strengths by ternary geopolymer binder of metakaolin, slag, and palm ash

Author:

Aboshia Ali Mohamed AliORCID,Rahmat Riza Atiq,Zain Muhammad Fauzi Mohd,Ismail Amiruddin

Abstract

Purpose The purpose of this paper is to develop an alternative new ternary geopolymer mortar (MKSP) to resolve a traditional mortar problem which exhibits several disadvantages, including poor strengths and surface microcracks and the CO2 air pollution. Design/methodology/approach The MKSP ternary binder was produced using metakaolin (MK), slag (S), and palm oil fuel ash (POFA) activated with an alkaline mixture of sodium silicate (Na2SiO3) and 10 M NaOH in a mass ratio of 2.5. Seven different mix proportions of MK, slag, and POFA were used to fabricate MKSP mortars. The water-to-binder ratio was varied between 0.4 and 0.5. The mortars were heat cured for 2 h at 80°C and then aged in air. Flexural stress and strain, mortars flow and compressive strength were tested. Furthermore, the mortars were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) analyses. Findings The results showed that the sample MKSP6, which contained 40 percent MK, 40 percent slag, and 20 percent POFA, exhibited high compressive strength (52 MPa) without any cracks and flexural strength (6.9 MPa) at 28 days after being cured for 2 h at 80°C; however, the MKSP7 mortar with optimal strength of 55 MPa showed some surface cracks . Further, the results of the XRD, SEM, and FTIR analyses indicated that the MKSP mortars primarily consisted of a crystalline (Si+Al) phase (70 percent) and a smaller amorphous (Si+Ca) phase (30 percent). Research limitations/implications The MKSP ternary geopolymer mix has three limitations as an importance of heat curing for development early strength, POFA content less than 20 percent to gain high normal strength and delaying the sitting time by controlling the slag content or the alkali activator type. Practical implications The use of geopolymer materials binder in a real building is limited and it still under research, Thus, the first model of real applied geopolymer cement in 2008 was the E-Crete model that formed by Zeobond company Australia to take the technology of geopolymer concrete to reality. Zeobond Pty Ltd was founded by Professor Jannie S.J. van (van Deventer et al., 2013), it was used to product precast concrete for the building structure. The second model was PYRAMENT model in 2002 by American cement manufacturer Lone Star Industries which was produced from the development carried out on inorganic alumino-silicate polymers called geopolymer (Palomo et al., 1999). In 2013 the third model was Queensland’s University GCI building with three suspended floors made from structural geopolymer concrete containing slag/fly ash-based geopolymer (Pathak, 2016). In Australia, 2014, the newly completed Brisbane West Wellcamp airport becomes the greenest airport in the world. Cement-free geopolymer concrete was used to save more than 6,600 tons of carbon emissions in the construction of the airport. Therefore, the next century will see cement companies developing alternative binders that are more environmentally friendly from a sustainable development point of view. Originality/value Production of new geopolymer binder of mortar as alternative to traditional cement binder with high early and normal strength from low cost waste materials, less potential of cracking, less energy consumption need and low carbon dioxide emission.

Publisher

Emerald

Subject

Building and Construction,Civil and Structural Engineering

Reference28 articles.

1. ASTMC1437-07 (2009), Standard Test Method for Flow of Hydraulic Cement Mortar, ASTM International, West Conshohocken, PA.

2. Effect of type, form, and dosage of activators on strength of alkali-activated natural pozzolans;Cement and Concrete Composites,2011

3. Performance of blended metakaolin/blastfurnace slag alkali-activated mortars;Cement and Concrete Composites,2016

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3