Author:
Elayyachy M.,El Kodadi M.,Hammouti B.,Ramdani A.,Elidrissi A.
Abstract
The inhibition of corrosion of steel in 1 M HCl solution by newly synthesised pyrazole derivatives has been studied by weight loss and polarisation techniques at 308°K. Its inhibitory power is compared to N,N′‐bis(3,5‐dimethylpyrazol‐1‐yl‐methyl)‐pentanolamine (Bipyr). The results obtained reveal that tripyrazole exhibits a good protection. Inhibition is found to increase with increase in inhibitor concentration. The inhibition behaviour of the compound has been explained on the basis of molecule size and charge density of adsorption active centres. The adsorption phenomenon obeys the Langmuir adsorption isotherm model.
Subject
Materials Chemistry,Surfaces, Coatings and Films
Reference17 articles.
1. Abdallah, M. and El‐Naggar, M.M. (2001), “Cu+2 cation + 3,5‐dimethyl pyrazole mixture as a corrosion inhibitor for carbon steel in sulfuric acid solution”, Mater. Chem. Phys., Vol. 71 No. 3, pp. 291‐8.
2. Aouniti, A., Hammouti, B., Brighli, M., Kertit, S., Berhili, F., El Kadiri, S. and Ramdani, A. (1996), “Inhibition of the acid corrosion of iron with new pyrazole derivatives”, J. Chim. Phys., Vol. 93 No. 7‐8, pp. 1262‐80.
3. Bode, R.H., Bol, J.E., Driessen, W.L., Hulsbergen, F.B., Reedijk, J. and Spek, A.L. (1999), “Formation of dinuclear copper(II) complexes from a macrocycle with built‐in pyrazole groups”, Inorg. Chem., Vol. 38 No. 6, pp. 1239‐43.
4. Chegorka, L.V. and Moiseeva, L.S. (1998), “Influence of pyrazole derivatives and mixtures composed on their basis on the corrosion of ferrous metals in sulfuric acid media”, Prot. Met., Vol. 34 No. 6, pp. 577‐80.
5. Dafali, A., Hammouti, B., Mokhlisse, R., Elkacemi, K. and Kertit, S. (2002), “Corrosion inhibition of copper in 3% NaCl solution by new bipyrazolic derivatives”, Anti‐corros. Meth. and Mat., Vol. 49 No. 2, pp. 96‐104.
Cited by
18 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献