Shape multistability in flexible tubular crystals through interactions of mobile dislocations

Abstract

Significance Crystalline sheets rolled up into cylinders occur in diverse biological and synthetic systems, including carbon nanotubes, biofilaments of the cellular cytoskeleton, and packings of colloidal particles. In this work, we show, computationally, that such tubular crystals can be programmed with reconfigurable shapes, due to motions of defects that interrupt the periodicity of the crystalline lattice. By identifying and exploiting stable patterns of these defects, we cause tubular crystals to relax into desired target geometries, a design principle that could guide the creation of versatile colloidal analogues to nanotubes. Our results suggest routes to tunable and switchable material properties in ordered, soft materials on deformable surfaces.