Instantons and the quantum bound to chaos

Author:

Sadhasivam Vijay Ganesh1ORCID,Meuser Lars12,Reichman David R.3,Althorpe Stuart C.1

Affiliation:

1. Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, United Kingdom

2. Department of Chemistry and Applied Biosciences, ETH Zurich (Swiss Federal Institute of Technology), Zürich 8093, Switzerland

3. Department of Chemistry, Columbia University, New York, NY 10027

Abstract

The rate at which information scrambles in a quantum system can be quantified using out-of-time-ordered correlators. A remarkable prediction is that the associated Lyapunov exponent λ that quantifies the scrambling rate in chaotic systems obeys a universal bound λ < 2 π k B T / ħ . Previous numerical and analytical studies have indicated that this bound has a quantum-statistical origin. Here, we use path-integral techniques to show that a minimal theory to reproduce this bound involves adding contributions from quantum thermal fluctuations (describing quantum tunneling and zero-point energy) to classical dynamics. By propagating a model quantum-Boltzmann-conserving classical dynamics for a system with a barrier, we show that the bound is controlled by the stability of thermal fluctuations around the barrier instanton (a delocalized structure which dominates the tunneling statistics). This stability requirement appears to be general, implying that there is a close relation between the formation of instantons, or related delocalized structures, and the imposition of the quantum-chaos bound.

Funder

St John's college, University of Cambridge

Publisher

Proceedings of the National Academy of Sciences

Subject

Multidisciplinary

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Thermal quenching of classical and semiclassical scrambling;Physical Review E;2024-07-26

2. Generalized quantum master equations can improve the accuracy of semiclassical predictions of multitime correlation functions;The Journal of Chemical Physics;2024-07-01

3. Quantum information scrambling and chemical reactions;Proceedings of the National Academy of Sciences;2024-04

4. Quantum scrambling across an energy barrier;Proceedings of the National Academy of Sciences;2023-12-18

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