Affiliation:
1. Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, People’s Republic of China
Abstract
Converting spent lithium-ion batteries (LIBs) and industrial wastewater into high-value-added substances by advanced electrocatalytic technology is important for sustainable energy development and environmental protection. Here, we propose a self-powered system using a home-made sulfide fuel cell (SFC) to power a two-electrode electrocatalytic sulfion oxidation reaction (SOR)–assisted hydrogen (H
2
) production electrolyzer (ESHPE), in which the sulfion-containing wastewater is used as the liquid fuel to produce clean water, sulfur, and hydrogen. The catalysts for the self-powered system are mainly prepared from spent LIBs to reduce the cost, such as the bifunctional Co
9
S
8
catalyst was prepared from spent LiCoO
2
for SOR and hydrogen evolution reaction (HER). The Fe–N–P codoped coral-like carbon nanotube arrays encapsulated Fe
2
P (C-ZIF/sLFP) catalyst was prepared from spent LiFePO
4
for oxygen reduction reaction. The Co
9
S
8
catalyst shows excellent catalytic activities in both SOR and HER, evidenced by the low cell voltage of 0.426 V at 20 mA cm
−2
in ESHPE. The SFC with Co
9
S
8
as anode and C-ZIF/sLFP as cathode exhibits an open-circuit voltage of 0.69 V and long discharge stability for 300 h at 20 mA cm
−2
. By integrating the SFC and ESHPE, the self-powered system delivers an impressive hydrogen production rate of 0.44 mL cm
−2
min
−1
. This work constructs a self-powered system with high-performance catalysts prepared from spent LIBs to transform sulfion-containing wastewater into purified water and prepare hydrogen, which is promising to achieve high economic efficiency, environmental remediation, and sustainable development.
Funder
The National Natural Science Foundation of China
深圳市科技创新委员会 | Natural Science Foundation of Shenzhen Municipality
GDSTC | Guangdong Provincial Introduction of Innovative Research and Development Team
Publisher
Proceedings of the National Academy of Sciences