Abstract
We studied the electrical transport of Fe4+δSe5single-crystal nanowires exhibiting √5 × √5 Fe-vacancy order and mixed valence of Fe. Fe4+δSe5compound has been identified as the parent phase of FeSe superconductor. A first-order metal-insulator (MI) transition of transition temperatureTMI∼ 28 K is observed at zero magnetic fields (B). Colossal positive magnetoresistance emerges, resulting from the magnetic field-dependent MI transition.TMIdemonstrates anisotropic magnetic field dependence with the preferred orientation along thecaxis. At temperatureT< ∼17 K, the state of near-magnetic field-independent resistance, which is due to spin polarized even at zero fields, preserves under magnetic fields up toB= 9 T. The Arrhenius law shift of the transition on the source-drain frequency dependence reveals that it is a nonoxide compound with the Verwey-like electronic correlation. The observation of the magnetic field-independent magnetoresistance at low temperature suggests it is in a charge-ordered state belowT∼ 17 K. The results of the field orientation measurements indicate that the spin-orbital coupling is crucial in √5 × √5 Fe vacancy-ordered Fe4+δSe5at low temperatures. Our findings provide valuable information to better understand the orbital nature and the interplay between the MI transition and superconductivity in FeSe-based materials.
Funder
Ministry of Science and Technology, Taiwan
Academia Sinica
Publisher
Proceedings of the National Academy of Sciences
Cited by
5 articles.
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