Energy dissipation bounds for autonomous thermodynamic cycles

Author:

Bryant Samuel J.ORCID,Machta Benjamin B.

Abstract

How much free energy is irreversibly lost during a thermodynamic process? For deterministic protocols, lower bounds on energy dissipation arise from the thermodynamic friction associated with pushing a system out of equilibrium in finite time. Recent work has also bounded the cost of precisely moving a single degree of freedom. Using stochastic thermodynamics, we compute the total energy cost of an autonomously controlled system by considering both thermodynamic friction and the entropic cost of precisely directing a single control parameter. Our result suggests a challenge to the usual understanding of the adiabatic limit: Here, even infinitely slow protocols are energetically irreversible.

Funder

National Science Foundation

Simons Foundation

Publisher

Proceedings of the National Academy of Sciences

Subject

Multidisciplinary

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