The Phosphorus and Arsenic Compounds of Sea-Water

Author:

Atkins W. R. G.,Wilson Edith G.

Abstract

1. Much of what was formerly considered to be phosphorus in organic combination, in sea-water, is in reality arsenic.2. Certain analyses giving high values for phosphate in sea-water and a June minimum very far from complete exhaustion of phosphate are vitiated by the inclusion of arsenate, as arsenomolybdate, in the phosphomolybdate precipitate.3. Arsenic in sea-water exists mainly in the form of arsenite. The arsenate present, if any, has hitherto been included in the results obtained for phosphate.4. Since arsenic is found in algæ and has been recorded as increasing in quantity with increase of depth it seems that the arsenic present in sea-water must undergo seasonal changes.

Publisher

Cambridge University Press (CUP)

Subject

Aquatic Science

Reference17 articles.

1. The Phosphate Content of Fresh and Salt Waters in its Relationship to the growth of the Algal Plankton

2. Chapman A. Chaston . 1926. On the presence of compounds of arsenic in marine crustaceans and shell fish. Analyst, 11, pp. 16. Received too late for mention in text. Records arsenious oxide 0·14 to 1·0 mg.p.l. in sea-water near Nore Lightship, Thames Estuary.

3. Zur Mikrobestimmung der Phosphorsäure.

4. Origines alimentaires de l'arsenic normal chez l'homme;Gautier;C.R. Acad. Sci.,1904

5. Quantitative Bestimmung der im Meerwassergelösten Phosphorsäure;Raben;Abt. Kiel,1916

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4. Dynamics of DOP;Biogeochemistry of Marine Dissolved Organic Matter;2002

5. Arsenic and Marine Organisms;Advances in Inorganic Chemistry;1996

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