Lattice Boltzmann modelling of colloidal suspensions drying in porous media accounting for local nanoparticle effects

Abstract

A two-dimensional (2-D) double-distribution lattice Boltzmann method (LBM) is implemented to study isothermal drying of a colloidal suspension considering local nanoparticle effects. The two LBMs solve isothermal two-phase flow and nanoparticle transport, respectively. The three local nanoparticle effects on the fluid dynamics considered in this paper are viscosity increase, surface tension drop and local drying rate reduction. The proposed model is first validated by the study of the drying of a 2-D suspended colloidal droplet for two different Péclet numbers, where the evolution of the diameter squared agrees well with experimental results. The model is further validated looking at drying of a colloid in a 2-D capillary tube with two open ends. Compared with experimental results, the best agreement in terms of deposition profile and drying time is obtained when considering all three nanoparticle effects. Afterwards, we apply the model to investigate the complicated drying of a colloidal suspension in a 2-D porous asphalt, considering all three local nanoparticle effects. The drying dynamics, resultant nanoparticle transport, accumulation and deposition are first analysed for a base case. Then a parametric study is conducted varying the initial nanoparticle concentration, porous medium contact angle, nanoparticle contact angle and nanoparticle diffusion coefficient. The influence of these parameters on drying dynamics, drying rate, deposition process and final deposition configurations is analysed in detail, together with the mutual influence of local nanoparticle behaviour. Finally, a unified relation between the average drying rate and the studied parameters is proposed and verified, covering the full parameter ranges of simulations.