Heat transfer, vapour diffusion and Stefan flow around levitating droplets near a heated liquid surface

Abstract

We consider a slowly condensing droplet levitating near the surface of an evaporating layer, and develop a mathematical model to describe diffusion, heat transfer and fluid flow in the system. The method of separation of variables in bipolar coordinates is used to obtain the series expansions for temperature, vapour concentration and the Stokes stream function. This framework allows us to determine temperature profiles and condensation rates at the surface of the droplet, and to calculate the upward force that allows the droplet to levitate. Somewhat counter-intuitively, condensation is found to be the strongest near the bottom of the droplet, which faces the hot liquid layer. The experimentally observed deviations from the classical law predicting the square of the radius to grow linearly in time are explained by the model. A spatially non-uniform phase change rate results in a contribution to the force not considered in previous studies, and comparable to droplet weight and the upward force calculated from the Stokes drag law. The levitation conditions are formulated accordingly, resulting in the prediction of levitation height as a function of droplet size without any fitting parameters. A simple criterion is formulated to define the parameter ranges in which levitation is possible. The results are in good agreement with the experimental data except that the model tends to slightly underpredict the levitation height.