Self-propulsion of an elliptical phoretic disk emitting solute uniformly

Abstract

Self-propulsion of chemically active droplets and phoretic disks has been studied widely; however, most research overlooks the influence of disk shape on swimming dynamics. Inspired by experimentally observed prolate composite droplets and elliptical camphor disks, we employ simulations to investigate the phoretic dynamics of an elliptical disk that emits solutes uniformly in the creeping flow regime. By varying the disk's eccentricity $e$ and the Péclet number $Pe$ , we distinguish five disk behaviours: stationary, steady, orbiting, periodic and chaotic. We perform a linear stability analysis (LSA) to predict the onset of instability and the most unstable eigenmode when a stationary disk transitions spontaneously to steady self-propulsion. In addition to the LSA, we use an alternative approach to determine the perturbation growth rate, illustrating the competing roles of advection and diffusion. The steady motion features a transition from a puller-type to a neutral-type swimmer as $Pe$ increases, which occurs as a bimodal concentration profile at the disk surface shifts to a polarized solute distribution, driven by convective solute transport. An elliptical disk achieves an orbiting motion through a chiral symmetry-breaking instability, wherein it repeatedly follows a circular path while simultaneously rotating. The periodic swinging motion, emerging from a steady motion via a supercritical Hopf bifurcation, is characterized by a wave-like trajectory. We uncover a transition from normal diffusion to superdiffusion as eccentricity $e$ increases, corresponding to a random-walking circular disk and a ballistically swimming elliptical counterpart, respectively.