Nitrogen Sulfide (NS) in Star Forming Regions

Abstract

Gas phase models of ion molecule chemistry have been rather successful in matching the observed abundances of small interstellar molecules containing carbon, hydrogen, and oxygen. However, the situation is somewhat less clear for nitrogen-containing species, partly because the important initiating reaction N+ + H2 is slightly endothermic; and for sulfur-containing molecules, where it remains uncertain whether it is necessary to invoke surface reactions on grains to match the observed abundances. As a relatively simple species, the abundance of nitrogen sulfide should provide a good test of the models of the coupled chemistry of nitrogen and sulfur. Until very recently only two molecules containing both these elements were known in the interstellar medium, NS and HNCS, and both have been observed only in Sgr B2. We have therefore undertaken a survey for interstellar NS in Galactic molecular clouds using the FCRAO 14-meter telescope. The 2Π1/2, J = 5/2 → 3/2, transition has in fact been detected in many regions of massive star formation (see table).