The approach to normality of the concentration distribution of a solute in a solvent flowing along a straight pipe

Abstract

Taylor (1953, 1954a) showed that, when a cloud of solute is injected into a pipe through which a solvent is flowing, it spreads out, so that the distribution of concentration C is eventually a Gaussian function of distance along the pipe axis. This paper is concerned with the approach to this final form. An asymptotic series is derived for the distribution of concentration based on the assumption that the diffusion of solute obeys Fick's law. The first term is the Gaussian function, and succeeding terms describe the asymmetries and other deviations from normality observed in practice. The theory is applied to Poiseuille flow in a pipe of radius a and it is concluded that three terms of the series describe C satisfactorily if Dt/a2 > 0·2 (where D is the coefficient of molecular diffusion), and that the initial distribution of C has little effect on the approach to normality in most cases of practical importance. The predictions of the theory are compared with numerical work by Sayre (1968) for a simple model of turbulent open channel flow and show excellent agreement. The final section of the paper presents a second series derived from the first which involves only quantities which can be determined directly by integration from the observed values of C without knowledge of the velocity distribution or diffusivity. The latter series can be derived independently of the rest of the paper provided the cumulants of C tend to zero fast enough as t → ∞, and it is suggested, therefore, that the latter series may be valid in flows for which Fick's law does not hold.