Numerical simulation of a concentrated emulsion in shear flow

Abstract

A three-dimensional computer simulation of a concentrated emulsion in shear flow has been developed for low-Reynolds-number finite-capillary-number conditions. Numerical results have been obtained using an efficient boundary integral formulation with periodic boundary conditions and up to twelve drops in each periodically replicated unit cell. Calculations have been performed over a range of capillary numbers where drop deformation is significant up to the value where drop breakup is imminent. Results have been obtained for dispersed-phase volume fractions up to 30% and dispersed- to continuous-phase viscosity ratios in the range of 0 to 5. The results reveal a complex rheology with pronounced shear thinning and large normal stresses that is associated with an anisotropic microstructure that results from the alignment of deformed drops in the flow direction. The viscosity of an emulsion is only a moderately increasing function of the dispersed-phase volume fraction, in contrast to suspensions of rigid particles or undeformed drops. Unlike rigid particles, deformable drops do not form large clusters.