Stress-Generated Ice Crystals in a Nearly Isothermal Two-Phase System

Abstract

The use of the two-phase system ice–water to illustrate the effects on equilibrium of both hydrostatic and non-hydrostatic stresses has been a recurrent theme in the history of thermodynamic theory. The effects of hydrostatic pressure on the melting point of ice are firmly established by theory and experiment. Those of non-hydrostatic stress are still a subject of debate today; several theorists have predicted ice re-crystallization under such stress, but the magnitude of any slight melting-point depression is not known with certainty. The recrystallization of ice caused by local variations in hydrostatic stress was predicted and experimentally confirmed over a century ago. Cavities deep within temperate glaciers provide a suitable environment for the occurrence of this latter phenomenon. A water-filled cavity intersected by a tunnel in nearly stagnant ice of the Blue Glacier, Washington State, U.S.A., was lined with large and unusual single ice crystals which apparently owe their origin to the effects of hydrostatic stress. Even the minute differences in pressure melting point around this cavity are adequate to remove the heat of fusion as ice forms within it. There is evidence that interstitial movement of melt water in the surrounding ice also contributes to the heat and mass transfer. The form of these crystals indicates that they grew into slightly supercooled water. It is suggested that this growth pattern is sustained by the existence of oriented stresses at the cavity walls.