Author:
Scott E Marian,Cook Gordon T,Naysmith Philip
Abstract
Proficiency testing is a widely used, international procedure common within the analytical chemistry community. A proficiency trial (which VIRI is) often follows a standard protocol, including analysis that is typically based on z-scores, with one key quantity, σp. From a laboratory intercomparison (sometimes called a proficiency trial), we hope to gain an assessment of accuracy (in this case, from dendro-dated samples), laboratory precision (from any duplicate samples), and generally, an overall measure of performance, including measurement variability and hence realistic estimates of uncertainty. In addition, given our stated aim of creating an archive of reference materials, we also gain a determination of consensus values for new reference materials.VIRI samples have been chosen to deliver these objectives and the sample ages included in the different stages, by design, spanned modern to background. With regard to pretreatment, some samples required intensive pretreatment (e.g. bone), while others required none (e.g. cellulose and humic acid). Sample size was not optimized, and indeed some samples were provided solely for accelerator mass spectrometry (AMS) measurement. In this sense, VIRI presented a more challenging exercise than previous intercomparisons, since by its design in stages, one can explore improvements (or deteriorations) over time in laboratory performance. At each stage, more than 50 laboratories have participated, with an increasing demographic shift towards more AMS and fewer radiometric laboratories.
Publisher
Cambridge University Press (CUP)
Subject
General Earth and Planetary Sciences,Archeology
Cited by
87 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献