Note on the Interpretation of the Density Matrix in the Many-Electron Problem

Abstract

When we treat an atom containing a number n of electrons by the method of the self-consistent field, we assume that each electron has its own particular “orbit,” specified by a wave function (q|r) in four variables q. These four variables are usually taken to be the three coordinates of the electron together with a variable describing the spin, but according to the transformation theory of quantum mechanics, they may be any four independent commuting functions of the coordinates, momenta and spin variables.