Improvements in calcined magnesite as a magnesium fertilizer

Abstract

SummaryA laboratory and glasshouse study investigated whether it was possible to improve the availability of magnesium from calcined magnesite (MgO). Samples varying from largely unchanged magnesite (MgCO3) to overburnt MgO were made by calcining small quantities of magnesite ore for up to 6 h at several temperatures between 500 and 1000 °C in the laboratory. The effect of calcining conditions on weight loss on ignition, particle size distribution, total, water-soluble and NH4+ -exchangeable Mg was determined and results compared with the current commercial oxide and kieserite (MgSO4. H2O).The results indicated that an oxide could be produced containing nearly double the amount of readily-exchangeable Mg of the oxide used at present. The analysis showed that the most reactive oxide was produced either by burning for 3 h at 700 °C or about half-an-hour at 800 °C, i.e. the minimum time at each temperature for complete conversion of the carbonate to the oxide. Either of these two oxides increased the Mg in plants of the three crops grown in the glasshouse by 0·3% on average, whereas plants given the commercial oxide increased it by only 0·2%. The three crops removed about 70% of the applied Mg from the most reactive oxides but only 50% of the Mg from the commercial oxide. The results of an incubation experiment suggested that burning at 700 °C for 3 h gave a marginally more reactive oxide than the short burn at 800 °C. However, the most reactive oxide produced supplied magnesium at a slower rate than kieserite. This may not necessarily be a disadvantage since most of the soils where Mg deficiency of sugar beet and similar crops is a potential problem need a Mg fertilizer which maintains or gradually increases soil Mg. Thus the improved oxide may bo suitable and a comparison in field experiments of the effects of kieserite and oxides produced under different calcining conditions is needed.