Changes in magnesium and calcium in soils of the Broadbalk wheat experiment at Rothamsted from 1865 to 1966

Abstract

SUMMARYChalk in the 0–9 in topsoil of Broadbalk has declined from nearly 5% in 1865 to less than 1 % in some plots in 1966, and fastest in plots given ammonium sulphate. Losses were equivalent to 5–8 cwt limestone/acre annually. The paper relates these rates to estimated anion losses, especially bicarbonate, from the plots. Af-ammonium acetate dissolved Ca and Mg from chalk particles in the soils. After correcting for this, exchangeable magnesium had increased during the first 50 years but decreased since 1914 in the F.Y.M. plot. In plots given none or 10 lb/acre of magnesium in fertilizer annually, exchangeable magnesium had changed little since 1865. Thissuggests that equilibrium was soon established between additions and losses of Mg in all except the F.Y.M. plots. Estimates of annual additions and losses of Mg from each plot show that an equilibrium is feasible without large gains from non-exchangeable soil resources. A method of calculating losses of Mg in the drainage using activity ratios and annual calcium losses was developed.