Powder diffraction data for fluorocomplexes of niobium IV: MNbF6 (M=Ca, Mg, Cd, Zn)

Author:

Goubard Fabrice,Llorente Samuel,Gaubicher Joël,Bizot Daniel,Chassaing Jean

Abstract

Four compounds in the hexafluoroniobates IV series MNbF6 (M=Ca, Mg, Cd, Zn) have been synthesized by solid-state reactions. CaNbF6, MgNbF6, and the “high temperature” form of CdNbF6 are isostructural with f.c. cubic NaSbF6 (space group Fm3m). ZnNbF6 and the room temperature form of CdNbF6 are isostructural with rhombohedral LiSbF6 (space group R3¯). Syntheses and powder diffraction data are reported.

Publisher

Cambridge University Press (CUP)

Subject

Condensed Matter Physics,Instrumentation,General Materials Science,Radiation

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