On the Effect of Continued Small Additions of Poisonous Substances on the Velocity of Gaseous Catalytic Reaction in Closed Vessels

Abstract

The Langmuir-Frenkel theory of surface action has been shown to involve a simple relation between the partial pressure of the catalyst poison, and the reduction in reaction velocity which results. Very interesting observations have been made by Beebe showing that the heat of adsorption of carbon monoxide on a reduced copper catalyst falls considerably and reaches a limiting value as the surface approaches saturation. Pease and Stewart have shown that the presence of less than one percent, of the total carbon monoxide that a given copper catalyst can adsorb will reduce the reaction velocity of the combination of hydrogen and ethylene at the surface of the copper by 88 per cent.