Water treatment with CoZnAl-LDH and its mixed metal oxide

Author:

Sharifi-Bonab Mina1,Aber Soheil1,Salari Dariush2,Khodam Fatemeh1

Affiliation:

1. Research Laboratory of Environmental Protection Technology (RLEPT), Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

2. Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

Abstract

Abstract CoZnAl-layered double hydroxide (LDH) was synthesized by homogeneous co-precipitation. CoZnAl-Mixed Metal Oxide (MMO) was prepared by calcining the LDH. The samples' structure and morphology were studied by analytical techniques including X-ray diffraction, N2 adsorption-desorption isotherm, scanning electron microscopy and UV–visible spectroscopy. Acid orange 7 (AO7) adsorption by as-prepared samples was studied. CoZnAl-MMO showed 526.32 mg/g adsorption capacity, higher than that of CoZnAl-LDH, 243.9 mg/g. Kinetic studies confirmed the pseudo-second-order and pseudo-first-order AO7 adsorption kinetics of the LDH and MMO, respectively. AO7 adsorption onto both LDH and MMO fitted the Langmuir isotherm model well. Band gap calculation confirmed the ability of this nano-MMO to operate in the visible light region. It displayed synergetic adsorption-photocatalytic performance under visible light and the removal efficiency was about 97%.

Funder

University of Tabriz

Publisher

IWA Publishing

Subject

Water Science and Technology

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