Synthesis, characterization, and performance of chitosan/nylon 6/polyurethane blend for the removal of chromium (VI) and lead (II) ions from aqueous solutions for enhanced kinetic adsorption studies

Author:

Jayakumar S.1,Sudarsan S.2,Sridhar B.3,Parthiban E.4,Prabu A. V.5,Jha Sudan6

Affiliation:

1. a Department of Chemistry, Rajalakshmi Engineering College, Chennai 602105, India

2. b Research Laboratory of Problems of Utilization of Modern Multicomponent Materials with a Complex Structure, South Ural State University, Chelyabinsk 454080, Russia

3. c Department of Electronics and Communication Engineering, MLR Institute of Technology, Hyderabad 500043, India

4. d Department of Chemistry, C. Abdul Hakeem College of Engineering and Technology, Melvisharam, Vellore 632509, India

5. e Department of Electronics and Communication Engineering, Koneru Lakshmaiah Education Foundation, Vaddeswaram, Guntur 522302, India

6. f Department of Computer Science and Engineering, Kathmandu University, Banepa, Kathmandu

Abstract

Abstract Adsorption is vital for the elimination of Cr6+ and Pb2+ ions in the contaminated solution medium. A ternary blend made up of chitosan, nylon 6 and polyurethane foam (CS/Ny 6/PUF) blend in the ratio of 2:1:1 has been investigated. These blends are used as an adsorbent due to the insoluble nature in acidic and basic medium. The adsorption efficacy was analyzed by modifying pH, contact time, and adsorbent dosage. The maximum uptake of metal ions has been exhibited in the pH range 5. An equilibrium adsorption statistic indicated that adsorption isotherm follows the Freundlich model. The adsorption kinetic parameters specified that the adsorption of chromium has shown pseudo-second-order and lead pseudo-first-order reaction.

Publisher

IWA Publishing

Subject

Filtration and Separation,Water Science and Technology

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