Hydrothermal-assisted synthesis of Sr-doped SnS nanoflower catalysts for photodegradation of metronidazole antibiotic pollutant in wastewater promoted by natural sunlight irradiation

Author:

Bouarroudj Tayeb1,Messai Youcef23,Aoudjit Lamine4,Zaidi Beddiaf5,Zioui Djamila4,Bendjama Amel6,Mezrag Samiha7,Chetoui Abdelmounaim8,Belkhettab Ilyas89,Bachari Khaldoun1

Affiliation:

1. a Scientific and Technical Research Center in Physico-Chemical Analyses (CRAPC), Industrial zone, PO-box 384 Bousmail, Tipaza, Algéria

2. b Laboratory for the Study of Surfaces and Interfaces of Solid Matter (LESIMS), Badji Mokhtar University, Annaba 23000, Algeria

3. c Laboratory of Surfaces and Interfaces Studies of Solid Materials (LESIMS), Faculty of Technology, Ferhat Abbas Setif 1 University, Setif 19000, Algeria

4. d Unité de Développement des Équipements Solaires, UDES/Centre de Développement des Energies Renouvelables, CDER, Bou-ismail, W. Tipaza 42415, Algeria

5. e Department of Physics, Faculty of Material Sciences, University of Batna 1, Batna, Algeria

6. f Research center in industrial technologies CRTI, P.O. Boxe 64, Cheraga, Algiers 16014, Algeria

7. g Département et Laboratoire de Métallurgie et Génie des Matériaux, Faculté des Sciences de l'Ingéniorat Université Badji Mokhtar-Annaba, BP 12 Annaba 23000, Algeria

8. h Research Center in Semiconductors Technology for Energetics (CRTSE), 02 Bd Dr Frantz Fanon, 7- Merveilles, Algiers, Algeria

9. i Laboratory of Electrochemistry-Corrosion, Metallurgy and Inorganic Chemistry, Faculty of Chemistry, USTHB, BP32, 16111 Algiers, Algeria

Abstract

Abstract In this study, we report a facile hydrothermal synthesis of strontium-doped SnS nanoflowers that were used as a catalyst for the degradation of antibiotic molecules in water. The prepared sample was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and ultraviolet–visible absorption spectroscopy (UV–Vis). The photocatalytic ability of the strontium-doped SnS nanoflowers was evaluated by studying the degradation of metronidazole in an aqueous solution under photocatalytic conditions. The degradation study was conducted for a reaction period of 300 min at neutral pH, and it was found that the degradation of metronidazole reached 91%, indicating the excellent photocatalytic performance of the catalyst. The influence of experimental parameters such as catalyst dosage, initial metronidazole concentration, initial reaction pH, and light source nature was optimized with respect to metronidazole degradation over time. The reusability of the strontium-doped SnS nanoflowers catalyst was investigated, and its photocatalytic efficiency remained unchanged even after four cycles of use.

Publisher

IWA Publishing

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