Affiliation:
1. Charles F. Kettering Research Laboratory, Yellow Springs, Ohio 45387, U.S.A.
Abstract
The heat of reaction (ΔH) of Fe(CN)63−, Methyl Viologen, FMN and FAD with S2O42− in aqueous buffer solutions was measured calorimetrically. In addition ΔH values for reduction of Fe(CN)63-, FMN and FAD by reduced Methyl Viologen were determined. The resulting calorimetric data and corresponding E0′ values were combined to yield thermodynamic data for these simple reducing agents in a form useful for applications to biological reactions. Thermodynamic data for the reduction of spinach ferredoxin are also presented.
Subject
Cell Biology,Molecular Biology,Biochemistry
Cited by
28 articles.
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