An anaerobic reaction between lipoxygenase, linoleic acid and its hydroperoxides-Reference-Cited by-同舟云学术

An anaerobic reaction between lipoxygenase, linoleic acid and its hydroperoxides

Published:1971-04-01 Issue:3 Volume:122 Page:327-332
ISSN:0306-3283
Container-title:Biochemical Journal
language:en
Short-container-title:

Author:

Garssen G. J.¹,Vliegenthart J. F. G.¹,Boldingh J.¹

Affiliation:

1. Laboratory of Organic Chemistry, State University of Utrecht, Croesestraat 79, Utrecht, The Netherlands

Abstract

In an anaerobic system soya-bean lipoxygenase together with linoleic acid induces a structural rearrangement of 13-hydroperoxyoctadeca-cis-9-trans-11-dienoic acid leading to the formation of 13-oxotrideca-cis(trans)-9-trans-11-dienoic acid and n-pentane as well as 13-oxo-octadeca-9,11-dienoic acid. It is proposed that the 13-peroxyoctadeca-cis-9-trans-11-dienoic acid radical formed through hydrogen radical abstraction by the linoleic acid radical is the key intermediate for these reactions.

Publisher

Portland Press Ltd.

Link

https://portlandpress.com/biochemj/article-pdf/122/3/327/770479/bj1220327.pdf

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