Syntheses, Characterization and Crystal Structures of Dicyanamide Bridged Polynuclear Copper(II) and Zinc(II) Complexes with Urease Inhibitory Activity
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Published:2022-09-26
Issue:3
Volume:69
Page:674-680
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ISSN:1580-3155
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Container-title:Acta Chimica Slovenica
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language:
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Short-container-title:ACSi
Author:
Zhang Li,Gu Yuqing,Feng Xinhui,Yang Ting,Li Xiaoyan,Wang Jing,You Zhonglu
Abstract
A pair of structurally similar dicyanamide bridged copper(II) and zinc(II) complexes [CuL(dca)]n (1) and [ZnL(dca)]n (2), were prepared from the fluorine containing Schiff base 5-fluoro-2-(((2-hydroxyethyl)imino)methyl)phenol (HL). The compounds were characterized by physico-chemical methods. Structures of the complexes were confirmed by single crystal X-ray diffraction. The Cu atom in complex 1 is in square pyramidal coordination, whereas the Zn atom in complex 2 is in trigonal bipyramidal coordination. The copper complex has effective Jack bean urease inhibitory activity, with IC50 value of 0.14 ± 0.12 μmol L–1.
Publisher
Slovenian Chemical Society
Cited by
1 articles.
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