Synthesis of 1-butoxy-4-tert-butylbenzene under The Effect of Multi-site Phase Transfer Catalysis System – A Kinetic Study
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Published:2020-04-26
Issue:2
Volume:15
Page:405-414
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ISSN:1978-2993
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Container-title:Bulletin of Chemical Reaction Engineering & Catalysis
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language:
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Short-container-title:Bull. Chem. React. Eng. Catal.
Author:
Sathiyaraj Manickam1,
Venkatesh Perumal1
Affiliation:
1. PG & Research, Department of Chemistry, Pachaiyappa’s College, Chennai, Tamil Nadu, 600 030, India
Abstract
Phase transfer catalysis technique proved to be a useful method for synthesizing various organic compounds under heterogeneous reactions and recognized as a viable environmentally friendly. The influence of a new multi site phase transfer catalyst (MPTC) is the synthesis of 1-butoxy-4-tertbutylbenzene from 4-tert-butylphenol with 1-bromobutane (BB) under heterogeneous solid-liquid condition using potassium hydroxide as a base at 60 °C. The higher conversion of 1-bromobutane was achieved by using the synergistic condition of multi-site phase transfer catalyst in better efficacy. The reaction rate enhanced by decreases the volume of water. The apparent the reaction rate was found to be pseudo-first order kinetics. The apparent rate constant was increased linearly with the increase in the concentration of various parameters, such as: MPTC, temperature, potassium hydroxide, and stirring speed. The activation energy (Ea) was also calculated through the Arrhenius plot. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Funder
Pachaiyappa’s Trust and Pachaiyappa’s College, Chennai, Tamil Nadu, India
Publisher
Bulletin of Chemical Reaction Engineering and Catalysis
Subject
Process Chemistry and Technology,Catalysis
Cited by
1 articles.
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