Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption-Reference-Cited by-同舟云学术

Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

Published:2024-01-29 Issue:1 Volume:19 Page:86-98
ISSN:1978-2993
Container-title:Bulletin of Chemical Reaction Engineering & Catalysis
language:
Short-container-title:Bull. Chem. React. Eng. Catal.

Author:

Nurhasni Nurhasni¹,Adawiah Adawiah²^ORCID,Wahyudin Wahyudin³,Hadriyani Rizka¹,Andriyani Leni¹,Fadhilla Rizkha¹,Zulys Agustino⁴^ORCID,Sukandar Dede¹

Affiliation:

1. Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia

2. Integrated Laboratory Centre, Faculty of Science and Technology UIN Syarif Hidayatullah Jakarta, Indonesia

3. Research Center for Advanced Materials, National Research and Innovation Agency, KST BJ Habibie, South Tangerang 15314, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia

4. Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424, Indonesia

Abstract

As an adsorbent material, Metal-Organic Framework (MOF) provides several advantages, such as large surface area and pore volume, as well as stability in aqueous systems both in acidic, basic, and neutral conditions. The research successfully made a metal organic framework (MOF) from chromium and perylene that was modulated by isonicotinic acid. This was done using three different methods: hydrothermal (Cr-PTC-HIna-HT), solvothermal (Cr-PTC-HIna-ST), and sonochemical (Cr-PTC-HIna-SC). The Cr-PTC-HIna-SC showed the greatest Pb2+ ion adsorption capacity. The optimum adsorption of Pb2+ ions occurred at 150 ppm Pb2+ ion concentration, pH 5, 90 minutes of contact time, and an adsorption capacity of 149.95 mg/g at 35 °C. The dominant adsorption isotherm model is the Langmuir isotherm model with R2 = 0.9867 and follows the pseudo-second-order. The selectivity test showed that Cr-PTC-HIna-SC MOF could adsorb more Cd2+ ions than Pb2+ ions, with 250 mg/g being the best amount.

Funder

UIN Syarif Hidayatullah Jakarta

Publisher

Bulletin of Chemical Reaction Engineering and Catalysis

Reference34 articles.

1. Adsorption of lead(II) and chromium(VI) from aqueous environment onto metal-organic framework MIL-100(Fe): Synthesis, kinetics, equilibrium and thermodynamics

2. Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution

3. Water Contaminant Elimination Based on Metal–Organic Frameworks and Perspective on Their Industrial Applications

4. Metal–Organic Frameworks for the Removal of Emerging Organic Contaminants in Water