Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst

Author:

Al Muttaqii Muhammad1ORCID,Marbun Maja Pranata2,Sudibyo Sudibyo3,Aunillah Asif4,Pranowo Dibyo5,Hasanudin Hasanudin6,Rinaldi Nino1,Bardant Teuku Beuna1

Affiliation:

1. Research Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, Indonesia

2. Department of Chemical Engineering, University of Sonan Bonang, East Java 62311, Indonesia

3. Research Center for Mining Technology, National Research and Innovation Agency (BRIN-Indonesia), South Lampung 35361, Indonesia

4. Research Center for Agroindustry, National Research and Innovation Agency (BRIN-Indonesia), Cibinong Jl. Raya Jakarta-Bogor KM 46, Cibinong 16911, Indonesia

5. Research Center for Horticultural and Estate Crops, National Research and Innovation Agency (BRIN-Indonesia), Cibinong 16911, Indonesia

6. Department of Chemistry, University of Sriwijaya, South Sumatera 30662, Indonesia

Abstract

In this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures. The results demonstrated that hydrocracking of Sunan candlenut oil using nano HZSM-5 and Fe-La/NHZ catalysts could be converted into aromatic hydrocarbons, and the reaction temperature affected hydrocarbon production. The aromatic compounds, such as propyl-benzene, 1-ethyl-3-methylbenzene, heptyl-benzene, 2-ethyl-naphthalene, etc., reached 35.51% over the Fe-La/NHZ_2 catalyst. In all cases, the zeolite-based catalysts are the most suitable to produce aromatic hydrocarbons. Metal impregnated (Fe and La) on nano HZSM-5 catalyst could improve the aromatics compounds due to increased metal and acid sites. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Funder

National Research and Innovation Agency-LPDP

Publisher

Bulletin of Chemical Reaction Engineering and Catalysis

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