Synthesis of Bimetallic Metal-Organic Frameworks (MOFs) La-Y-PTC for Enhanced Dyes Photocatalytic Degradation

Author:

Adawiah Adawiah1ORCID,Gunawan Muhammad Shofyan2,Aziz Isalmi2,Oktavia Wulandari2

Affiliation:

1. Integrated Laboratory Centre, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95, Ciputat, South Tangerang 15412, Indonesia

2. Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95, Ciputat, Tangerang Selatan 15412, Indonesia

Abstract

Metal-Organic Frameworks (MOFs) is widely utilized as photocatalysts in dye photocatalytic degradation. This study successfully synthesized bimetallic MOFs La-Y-PTC by the solvothermal method. The synthesized La-Y-PTC has a diffractogram pattern with a value of 2θ = 5.69°; 9.57°; 16.8°; 20.05°; 24.8°; 26.15°; 29.77° and 41.93° with a crystal size of 21.45 nm. The La-Y-PTC has symmetric and asymmetric (COO−) at 1591 and 1433 cm−1, La−O and Y−O groups at 596 and 659 cm−1 and a band gap energy of 2.16 eV. Scanning Electron Microscope analysis showed that the morphology of La-Y-PTC is spherical with a particle size of 354.307 nm. La-Y-PTC degrades methylene blue and methyl orange at pH 2 with a degradation efficiency of 69.57% and 93.63%, respectively, under 250 watts of mercury lamp irradiation for 180 min with hydroxyl radical species as a dominant species that play a role in methylene blue and methyl orange degradations. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

Funder

UIN Syarif Hidayatullah Jakarta

Publisher

Bulletin of Chemical Reaction Engineering and Catalysis

Subject

Process Chemistry and Technology,Catalysis,General Chemistry

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