Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole-Reference-Cited by-同舟云学术

Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole

Published:2018-05-01 Issue:2 Volume:47 Page:73-78
ISSN:2357-3791
Container-title:Revista Colombiana de Química
language:
Short-container-title:Rev. colomb. quim.

Author:

Ceroni Galloso Mario^ORCID,Angulo-Cornejo Jorge Reynaldo,Lino-Pacaheco Maria Nieves^ORCID,Villanueva Huerta Claudia Cecilia^ORCID,Casimiro Soriano Enzo Martín^ORCID

Abstract

Se sintetizó un nuevo compuesto de coordinación de plata, [Ag(sac)(pbi)], por reacción de sacarinato de plata(I) con 2-(2-piridil)bencimidazol (pbi) con un rendimiento de 64%. La caracterización se realizó por análisis elemental, espectroscopia IR, UV-Visible, XPS, 1H-RMN y 13C-RMN. De acuerdo con los resultados obtenidos la plata está coordinada a través de tres átomos de nitrógeno, uno del sacarinato y los dos restantes del 2-(2-piridil)-bencimidazol formando con este ligando un anillo quelato de cinco miembros.

Publisher

Universidad Nacional de Colombia

Subject

General Chemistry

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