FT-IR Spectroscopic Study on Some 4-(3-Cyclohexen-1-yl)pyridine Metal(II) Tetracyanonickelate Complexes

Author:

Şentürk Şükrü1,Parlak C.23,Aytekin M. Türkay2,Şenyel Mustafa23

Affiliation:

1. Department of Physics, Dumlupınar University, Kutahya, Turkey

2. Department of Physics, Science Faculty, Anadolu University, Eskişehir, Turkey

3. Plant, Drug and Scientific Research Centre, Anadolu University, Eskişehir, Turkey

Abstract

New Hofmann-type complexes in the form of M(4-Chpy)2Ni(CN)4 [where 4-Chpy = 4-(3- cyclohexen-1-yl)pyridine and M = Ni, Co] were prepared in powder form, and their infrared spectra are reported in the range of 4000 - 400 cm−1. The spectral findings suggest that these compounds are similar in structure to the Hofmann-type complexes, and their structure consists of polymeric layers |M-Ni(CN)4| with the 4-(3-cyclohexen-1-yl)pyridine molecule bound to the metal atom (M). PACS: 33.20.Ea, 33.20.Tp, 82.75-z

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 9 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. FT-IR and Raman spectroscopic analysis of some Hofmann type complexes;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2012-12

2. Vibrational spectroscopic analysis of some Hofmann–Td type complexes;Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2012-11

3. Self-Assembly of 1,4-Benzenedimethanethiol Self-Assembled Monolayers on Gold;Langmuir;2010-03-03

4. FT-IR spectroscopic investigation of some Hofmann type complexes: M(2-(1-Cyclohexenyl)ethylamine)2Ni(CN)4 (M=Ni, Co);Journal of Molecular Structure;2008-12

5. FT-IR spectroscopic investigation of some Hofmann type complexes: M(1-phenylpiperazine)2Ni(CN)4 (M=Ni, Co, Cd, Pd or Mn);Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy;2008-07

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