Supramolecular architecture based on high-lacunary sandwich-type building blocks: synthesis, characterization, and properties-Reference-Cited by-同舟云学术

Supramolecular architecture based on high-lacunary sandwich-type building blocks: synthesis, characterization, and properties

Published:2016-05-05 Issue:7 Volume:71 Page:783-788
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Wu Qiong¹,Miao Xisong²,Wang Hai³,Wu Yongmei⁴,Li Jun⁵,Lu Jing¹,Zhou Qingyan¹,Ju Hongping⁵

Affiliation:

1. Department of Chemical Science and Technology , Kunming University , Yunnan, Kunming 65200, P.R. China

2. Medical School, Kunming University , Yunnan, Kunming 65200, P.R. China, Fax: +86-871-65098476

3. Key Laboratory of Yunnan Provincial Higher Education Institutions for Organic Optoelectronic Materials and Devices , Kunming University , Yunnan, Kunming 65200, P.R. China

4. School of International Cultures and Education, Yunnan University of Finance and Economics , Yunnan, Kunming 650221, P.R. China

5. Medical School, Kunming University , Yunnan, Kunming 65200, P.R. China

Abstract

Abstract The new supramolecular compound [Fe2(AsMo7O27)2](H2en)2(NH4)8·6H2O (1) (en = ethylenediamine) has been synthesized in aqueous solution and characterized by elemental analysis, thermal analysis, and single crystal X-ray diffraction. The structural analysis has revealed that 1 represents the first example of a polyoxometalate-based sandwich-type supramolecular hybrid constructed from hexalacunary building blocks. Owing to the presence of ethylenediammonium cations, the [Fe2(AsMo7O27)2]12– units are stabilized by multiple circular hydrogen bonds extending the structure into a 2D supramolecular framework. The magnetic properties and antitumor activities of 1 have also been studied.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2015-0202/pdf

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