The ternary system Tm–Ni–In at 870 K

Author:

Tyvanchuk Yuriy B.1,Lukachuk Maryana2,Pöttgen Rainer2,Szytuła Andrzej3,Kalychak Yaroslav M.1

Affiliation:

1. Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya 6, UA-79005 Lviv, Ukraine

2. Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany

3. Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348 Kraków, Poland

Abstract

Abstract The isothermal section of the Tm–Ni–In system at T = 870 K was constructed. Nine ternary compounds: Tm10Ni9In20, TmNi1–0.60In1–1.40, Tm2Ni2In, Tm2Ni1.78In, Tm5Ni2In4, Tm11Ni4In9, Tm4.83Ni2In1.17, Tm6Ni2In and Tm14Ni3In3 exist in the system at the temperature of investigation. Solid solutions with In/Ni and Tm/In mixing were noticed for numerous compounds. A broad substitution of Ni for In was observed for TmNi1–0.60In1–1.40, and of Tm for In for the TmNi2–TmNi4In section. An interstitial solid solution Tm x NiIn, based on binary equiatomic NiIn, extends up to 8 at.% Tm (x = 0.17). The magnetic properties of TmNiIn, Tm2Ni2In and Tm5Ni2In4 are also reviewed.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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