Affiliation:
1. Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
2. Institut de Chimie de la Matière Condensée de Bordeaux, CNRS, Université Bordeaux, ICMCB, UPR 9048, F-33600 Pessac, France
Abstract
Abstract
Equiatomic CeTX intermetallics with the hexagonal ZrNiAl type structure are formed with electron-rich transition metals (T) and X = Mg, Zn, Cd, Al, Ga, In, Tl, Sn, and Pb. Their crystal chemistry, chemical bonding, magnetic and electrical properties, and formation of solid solutions are reviewed. The results of 119Sn Mössbauer spectroscopy, high-pressure studies, and hydrogenation reactions are presented.
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