New transition metal oxide fluorides with ReO3-type structure-Reference-Cited by-同舟云学术

New transition metal oxide fluorides with ReO3-type structure

Published:2016-03-25 Issue:5 Volume:71 Page:457-461
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Nakhal Suliman¹,Lerch Martin¹

Affiliation:

1. Institut für Chemie , Technische Universität Berlin , D-10623 Berlin, Germany

Abstract

Abstract The new niobium oxide fluorides MNbO2F4 [M = (Cr, Fe)], CrNb2O4F5, and Fe2Nb3O6F9 were prepared by treatment of chromium or iron nitrate with Nb-containing hydrofluoric acid solutions. Crystal structures were investigated by means of X-ray powder diffraction. All new compounds can be structurally refined in the cubic ReO3-type. The iron niobium oxide fluorides are reddish orange, and chromium containing phases exhibit a light green color. The niobium atoms are in the highest formal oxidation state.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2015-0215/pdf

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1. Perovskite-related ReO3-type structures;Nature Reviews Materials;2020-01-22

2. ChemInform Abstract: New Transition Metal Oxide Fluorides with ReO3-Type Structure.;ChemInform;2016-07