Chromium(III) complexes with 1,2,4-diazaphospholide and 2,6-bis(N-1,2,4-diazaphosphol-1-yl) pyridine ligands: synthesis, X-ray structural characterization, EPR spectroscopy analysis, and magnetic susceptibility studies
Author:
Su Jing1, Duan Lian1, Zheng Wenjun2
Affiliation:
1. Institute of Organic Chemistry and School of Chemical and Materials Science , Shanxi Normal University , Linfen, Shanxi Province 041004, P.R. China 2. Institute of Organic Chemistry and School of Chemical and Materials Science , Shanxi Normal University and Key Laboratory of Magnetic Molecules and Magnetic Information Material , Ministry of Education, Gongyuan Street 1, Linfen, Shanxi Province 041004, P.R. China,
Abstract
Abstract
Three chromium(III) 1,2,4-diazaphospholide complexes were prepared: 3,5-di-tert-butyl-1,2,4-diazaphospholide chromium(III) dichloride [(η
2-3,5-tBu2dp)Cr(THF)2Cl2] (1), 3,5-di-phenyl-1,2,4-diazaphospholide chromium(III) dichloride [(η
2-3,5-Ph2dp)Cr(THF)2Cl2] (2), and 2,6-bis(N-1,2,4-diazaphosphol-1-yl)pyridine chromium(III) trichloride {[2,6-bis(N-1,2,4-diazaphosphol-1-yl)pyridine]CrCl3} (3). X-ray diffraction analysis has shown that these six-coordinate complexes each have a pseudo-octahedral configuration. Electron paramagnetic resonance (EPR) spectroscopy data for complex 1 for the paramagnetic S = 3/2 system (d
3 electron configuration) confirm a Cr(III) center in the octahedral coordination environment. The magnetic susceptibility of complex 1 followed the Curie–Weiss law well between 25 and 300 K. The magnetic moment of 1 was found to be close to the spin-only magnetic moment expected for three unpaired electrons (3.87 μB).
Publisher
Walter de Gruyter GmbH
Subject
General Chemistry
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