Affiliation:
1. Anorganische Chemie II, Universität Bayreuth, D-95440 Bayreuth, Germany
Abstract
Abstract
Care should be taken on recording the sometimes elusive 13C NMR signals for boron-bonded carbon atoms, since it is easy to extract information about coupling constants 1
J(13C,11B) by measuring the respective line widths of 13C(B-C) and 11B NMR signals. This information can be confirmed by quantum-chemical calculations [B3LYP (6-311+G(d,p) level of theory] of
n
J(13C,11B) in organoboranes and tetraorganoborates. For the latter, the signs for n = 2, 3, 4 were experimentally determined.
Reference21 articles.
1. R. Köster, Houben-Weyl Methoden der Organischen Chemie, Organobor-Verbindungen I, Band 13, Teil 3a, Thieme, Stuttgart, 1982.
2. H. C. Brown, Organic Syntheses via Boranes, Wiley, New York 1975.
3. A. Suzuki, Heterocycles2010, 80, 15–43.
4. H. Nöth, B. Wrackmeyer, Nuclear Magnetic Resonance Spectroscopy of Boron Compounds, in NMR – Basic Principles and Progress, (Eds.: P. Diehl, E. Fluck, R. Kosfeld), Vol. 14, Springer, Berlin, 1978.
5. H.-O. Kalinowski, S. Berger, S. Braun, 13C-NMR-Spektroskopie, Thieme, Stuttgart, 1984.
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