Highly conjugated carbazole-based monomers for the control of nanotubular surface structures by soft template electropolymerization

Abstract

Abstract In this work, a bioinspired approach is used to prepare nanotubular structures with tunable hydrophobicity and water adhesion by a soft template surfactant-free electropolymerization in organic solvent. Various highly conjugated carbazole-based molecules are used as monomer. The presence of water in the organic solvent enables the formation of porous and rough nanostructures. Their shapes depend essentially on the nature of the monomer and the way it polymerizes. Various morphologies were obtained from nanoparticles network to horizontally or vertically aligned nanotubes. The nanostructured surfaces reach superhydrophobic properties and their dynamical behavior varies with the monomer from sticky to slippery. For example, using 9,3′:6′,9″-tercarbazole (TC) very long nanotubes are observed but their number is higher at constant potential. At high deposition charge, it is observed that most of the tubes are even collapsed leading to a strong increase of surface hydrophobicity with apparent contact angle up to 143° with strong water adhesion comparable to rose petals or gecko foot.