Die Kristallstruktur von Dinatriumdi-μ-azido-tetraazido-bis- (hexamethy lentetramin) - dicuprat (II) - trihydrat, Na2[Cu2(N3)6(C6H12N4)2]·3 H2O, einem pentakoordinierten Kupfer(II)- Komplex / The Crystal Structure of Sodium Di-μ-azido-tetraazidobis(hexamethylenetetramine) dicuprate(II)-tri hydrate, Na2[Cu2(N3)6(C6H12N4)2]·3H2O, a Pentacoordinated Copper(II) Complex-Reference-Cited by-同舟云学术

Die Kristallstruktur von Dinatriumdi-μ-azido-tetraazido-bis- (hexamethy lentetramin) - dicuprat (II) - trihydrat, Na2[Cu2(N3)6(C6H12N4)2]·3 H2O, einem pentakoordinierten Kupfer(II)- Komplex / The Crystal Structure of Sodium Di-μ-azido-tetraazidobis(hexamethylenetetramine) dicuprate(II)-tri hydrate, Na2[Cu2(N3)6(C6H12N4)2]·3H2O, a Pentacoordinated Copper(II) Complex

Published:1982-01-01 Issue:1 Volume:37 Page:110-111
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Pickardt Joachim¹

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, Straße des 17. Juni 135, D-1000 Berlin 12

Abstract

By reaction of cupric chloride with sodium azide and hexamethylenetetramine in aqueous solution crystals of the title compound could be obtained. An X-ray analysis showed the compound to contain a dimeric cuprate(II) anion with terminal as well as bridging azido groups.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1982-0119/pdf

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