Affiliation:
1. Institut für Anorganische Chemie und Strukturchemie der Universität Düsseldorf, Universitätsstraße 1, D-4000 Düsseldorf
Abstract
Abstract
The crystal structure of 2 SbBr3 · biphenyl consists of pyramidally shaped SbBr3 molecules and planar biphenyl molecules which form a centrosymmetric complex through bonding of the Sb atoms to the phenyl rings. The distance of the Sb atoms to the phenyl ring planes is 323 pm. Taking into account intramolecular bonds Sb-Br at an average of 250.9 pm, an intermolecular Sb···Br contact at 369.5 pm and the π-donor-acceptor inter-action the Sb coordination is distorted ψ-octahedral. The structure is discussed with regard to related compounds.
Cited by
15 articles.
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