Übergangsmetall-Carben-Komplexe, CXXIII [1] Dicarbenoktacarbonyldirhenium-Komplexe / Transition Metal Carbene Complexes, CXXIII [1] Dicarbeneoctacarbonyldirhenium Complexes-Reference-Cited by-同舟云学术

Übergangsmetall-Carben-Komplexe, CXXIII [1] Dicarbenoktacarbonyldirhenium-Komplexe / Transition Metal Carbene Complexes, CXXIII [1] Dicarbeneoctacarbonyldirhenium Complexes

Published:1982-05-01 Issue:5 Volume:37 Page:627-630
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Fischer Ernst Otto¹,Rustemeyer Paul¹

Affiliation:

1. Anorganisch-Chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, D-8046 Garching

Abstract

The reaction of Re2(CO)10 with LiSi(C6H5)3 and subsequent alkylation by (C2H5)3OBF4 yields not only (CO)9Re2C(OC2H5)Si(C6H5)3 but also Re1-ax,Re2-eq-[C(OC2H5)Si(C6H5)3]2(CO)8Re2 (1). The analogous isomeric complexes Re1-ax-[C(OC2H5)C6H4CH3]-Re2-eq-[C(OC2H5)Si(C6H5)3](CO)8Re2 (2) and Re1-ax-[C(OC2H5)Si(C6H5)3]-Re2-eq-[C(OC2H5)C6H4CH3](CO)8Re2 (3) are obtained by treatment of eq- or ax-(CO)9Re2C(OC2H5)Si(C6H5)3 with LiC6H4CH3 and subsequent alkylation by (C2H5)3OBF4. Reaction conditions, and properties and spectroscopic data of the new compounds are reported

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1982-0517/pdf

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1. Silicon derivatives of the metals of groups 1 and 2;Coordination Chemistry Reviews;1995-11

2. 4 Rhenium;Coordination Chemistry Reviews;1987-11

3. Dioxy carbene complexes from reactions of Fe(CO)5, Mn2(CO)10, Re2(CO)10 and Ru3(CO)12 with oxirane;Inorganica Chimica Acta;1985-05

4. μ‐Allenyliden‐dimangan‐ und ‐dirhenium‐Komplexe;Chemische Berichte;1984-12

5. Übergangsmetall-carben-komplexe;Journal of Organometallic Chemistry;1983-05