Notizen: Einkristall-Daten der Hochdruck-Hochtemperaturphase von CaSi2 / Structural Refinement of the High Pressure-High Temperature Phase of CaSi2-Reference-Cited by-同舟云学术

Notizen: Einkristall-Daten der Hochdruck-Hochtemperaturphase von CaSi2 / Structural Refinement of the High Pressure-High Temperature Phase of CaSi2

Published:1982-11-01 Issue:11 Volume:37 Page:1487-1488
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Evers Jürgen¹,Oehlinger Gilbert¹,Weiss Armin¹

Affiliation:

1. Institut für Anorganische Chemie der Universität, Meiserstraße 1, D-8000 München 2

Abstract

The high pressure-high temperature phase of CaSi2 is a representative of the α-ThSi2 type of structure. Single crystals grown at 40 kbar and 1000 °C enabled a structural refinement which leads to interatomic distances Si-Si: 229.9(1) pm (1 × ) and 240.0(1) pm (2 × ), Ca-Si: 309.4(4) pm (4 x ) and 323.9(4) pm (8 × ), Ca-Ca: 400.3(3) pm (4 × ) and 428.3(3) pm (4 × ).

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1982-1123/pdf

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