Synthesis and crystal structures of non-symmetric 1,3-di(alkyloxy)imidazolium salts-Reference-Cited by-同舟云学术

Synthesis and crystal structures of non-symmetric 1,3-di(alkyloxy)imidazolium salts

Published:2017-07-27 Issue:8 Volume:72 Page:617-626
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Jochriem Markus¹,Kirchler Christian G.¹,Laus Gerhard²,Wurst Klaus¹,Kopacka Holger¹,Müller Thomas¹,Schottenberger Herwig¹

Affiliation:

1. Faculty of Chemistry and Pharmacy , University of Innsbruck , 6020 Innsbruck , Austria

2. Faculty of Chemistry and Pharmacy, University of Innsbruck , 6020 Innsbruck , Austria , Fax: +43 512 507 57099

Abstract

Abstract A series of non-symmetric 1,3-di(alkyloxy)imidazolium salts were synthesized by stepwise alkylation of 1-hydroxyimidazole-3-oxide. The quaternary salts were subsequently functionalized by bromination in 2-position. A 2-azidoimidazolium salt and an imidazoline-2-thione were prepared exemplarily. Crystal structures of two 2-bromo-1-alkyloxy-3-methyloxyimidazolium tribromides and a mercury(II)-thione complex have been determined by X-ray diffraction.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2017-0089/pdf

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