Crystal structure and luminescence properties of a new dinuclear bismuth(III) coordination polymer containing three types of ligands

Author:

Feng Yu-Quan1,Zhong Zhi-Guo2,Wang Hong-Wei2,Xing Zheng-Zheng2,Wang Lu2

Affiliation:

1. College of Chemistry and Pharmacy Engineering , Nanyang Normal University , Nanyang 473061 , P. R. China , Tel.: +86-377-6351-3583

2. College of Chemistry and Pharmacy Engineering , Nanyang Normal University , Nanyang 473061 , P. R. China

Abstract

Abstract A new dinuclear bismuth(III) coordination polymer {[Bi(H2O)]2(C7H3NO4)2(C12H8N2)2(N3)2·2H2O} n (1) containing three types of ligands has been synthesized using a solvothermal method and characterized by infrared (IR) spectroscopy, energy-dispersive X-ray spectroscopy, and X-ray single-crystal structural analysis. The compound can be viewed as a three-dimensional supramolecular network that is constructed by Bi3+ cations, N3 anions, pyridine-2,5-dicarboxylate (2,5-pdc2−), and 1,10-phenanthroline (phen) ligands. Moreover, the luminescence properties, quantum yield, luminescence decay, and thermal stabilities of 1 were also investigated.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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