GdCuMg with ZrNiAl-type structure – an 82.2 K ferromagnet

Author:

Stein Sebastian1,Heletta Lukas1,Pöttgen Rainer1

Affiliation:

1. Institut für Anorganische und Analytische Chemie , Universität Münster , Corrensstrasse 30 , 48149 Münster , Germany

Abstract

Abstract GdCuMg has been synthesized by induction-melting of the elements in a sealed niobium ampoule followed by annealing in a muffle furnace. The sample was studied by powder and single crystal X-ray diffraction: ZrNiAl type, P6̅2m (a=749.2(4), c=403.3(1) pm), wR2=0.0242, 315 F 2 values and 15 variables. Temperature dependent magnetic susceptibility measurements have revealed an experimental magnetic moment of 8.54(1) μB per Gd atom. GdCuMg orders ferromagnetically below T C=82.2(5) K and based on the magnetization isotherms it can be classified as a soft ferromagnet.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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